Photoelectron spectroscopy of transition metal complexes
نویسندگان
چکیده
منابع مشابه
Femtosecond absorption spectroscopy of transition metal charge-transfer complexes.
Our research is concerned with the application of femtosecond time-resolved absorption techniques to the study of the photophysics of transition metal complexes. The focus is to understand the events that characterize the process of excited-state evolution from the time a photon is absorbed by a molecule to the formation of the lowest-energy excited state of the system. This Account describes o...
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Recent attosecond-streaking spectroscopy experiments [A. L. Cavalieri, Nature (London) 449, 1029 (2007)10.1038/nature06229] using copropagating extreme ultraviolet (XUV) and infrared (IR) pulses of variable relative delay have measured a delay of approximately 100 attoseconds between photoelectrons emitted by a single XUV photon from localized core states and delocalized conduction-band states ...
متن کاملPhotoelectron Spectroscopy of Alkali Metal Cluster Anions
ABSTRACf. We present the photoelectron (photodetacment) spectra of K2:-19 recorded using 2.540 eV photons. These spectra are highly structured, providing a wealth of information about the electronic structure of alkali metal clusters, including adiabatic electron affinities and electronic spliuings for each size. Spectral assignments have been made with guidance from theory. For the smaller clu...
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Andersson, T. 2012. Free Metal Clusters Studied by Photoelectron Spectroscopy. Acta Universitatis Upsaliensis. Digital Comprehensive Summaries of Uppsala Dissertations from the Faculty of Science and Technology 992. 55 pp. Uppsala. ISBN 978-91-554-8525-2. Clusters are aggregates of a finite number of atoms or molecules. In the present work, free clusters out of metallic parent materials have be...
متن کاملTransition Metal Imido Complexes
A wide range of transition metal imido (TMI) complexes is studied using ab initio molecular orbital (MO) calculations. The main computational point of interest is the further testing of effective core potentials (ECPs) and valence basis sets to allow for the accurate calculation of properties for reasonably sized transition metal complexes. On the chemical side, several results from the study a...
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ژورنال
عنوان ژورنال: Pure and Applied Chemistry
سال: 1979
ISSN: 1365-3075,0033-4545
DOI: 10.1351/pac197951112183